Facing the complicated market environment, the entrepreneurial practice of college students shows that the entrepreneurial executive ability is relatively weak. This paper aims to analyze entrepreneurial executive ability by AHP and relevant fuzzy evaluation. Through discussing factors which affects executive ability, a new definition of executive ability based on process is put forward, and accordingly, evaluation index system of executive ability is constructed. Weight coefficient of index system has been obtained by the combined method of questionnaire investigation and AHP, and the relevant fuzzy evaluation model has been established. Using two-dimensional quadrant analysis and relevant coefficient analysis, selecting approaches and the ways of improved object are pointed out, and the concrete suggestions have been put forward.